What would be the expected outcome of the reductive amination if the substrate is the one shown below? Draw the structure and briefly explain your reasoning. རྒྱ་ཡིག་.. TBS
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- Be sure to answer all parts. What ammonium salt is formed when this biologically active amine is treated with H2SO4? Be sure to include the charge(s). draw structure ...An aqueous solution of a primary or secondary amine reacts with an acyl chloride to form an amide as the major product. However, if the amine is tertiary, an amide is not formed. What product is formed? Explain.If a quaternary ammonium ion can undergo an elimination reaction with a strong base, why can’t a protonated tertiary amine undergo the same reaction?
- 1. Give the order of basicity of alkaloids based on the R-groups attached to the amino functional group. Based on your knowledge in organic chemistry, explain the reason why one is more or less basic as compared to the other.Draw the structures of the products when each of the following amides undergo hydrolysis with NaOH. You may want to reference (Page) Section 18.6 while completing this problem. ▼ CH3 0 CH,—CH,—CH—C—NH, Draw the molecules on the canvas by choosing buttons from the Tools (for bonds and charg www NN [1] Submit Part B Request Answer H 120 EXP CONT + Marvin JS by ChemAxon • & H H 120 EXP CONT C N O S CI Br - PFL O CH₂ CH3 CH3-CH₂-CH₂-C-N-CH₂-CH3 Draw the molecules on the canvas by choosing buttons from the Tools (for bonds and charg Р H C Z OThe structure of Amines are classified as primary (1), secondary (2), and tertiary (3) based on the number of R group including example that concept that seemed difficult to you at first, but then after working on the concept, you were able to master it. Include a description of what made the concept difficult at first, and then discuss what you did in order to better understand the concept.
- Which of these amines would produce the salt with the highest melting point if mixed separately with hydrochloric acid (HCI)? Based on the structure and properties of the resulting ammonium salts, explain your reasoning NH₂ NExplain why the boiling point of propanamide, CH3CH2CONH2, is considerably higher than the boiling point of N,Ndimethylformamide, HCON(CH3)2 (213 °C vs. 153 °C), even though both compounds are isomeric amides.Why is the amine N atom more nucleophilic than the amide N atom in CH3CONHCH2CH2CH2NHCH3?
- Define the simplest method to synthesize an amine ?1. Biogenic Amines are inactivated primarily by a. Sulfonation b. Glucoronidation c. Aromatic hydroxylation d. Methylation 2. A drug can exert its pharmacological effect only if it is a. Protein bound b. Protein unbound c. Free drug d. Both B & C e. Both A & C 3. In order for the drug to be ready and available for absorption, it must be release first from its dosage form with the exception of: a. Capsule b. Tablet c. Solution d. Suspension 4. All of the following are true, except a. Solubility increase with decrease particle size b. Solubility increase with increase surface area c. Solubility increase with increase particle size d. Solubility decrease with decrease surface area 5. The rate in which the drug appears in the bloodstream is also known as a. Half-life b. Potency c. Bioavailability d. Area under the curvePlease follow all directions. Thanks! Draw structural formulas for the two compounds you could use to prepare the amine shown by reductive amination. NH, OH • You do not have to consider stereochemistry. • Do not include the reducing agent in your answer. • If there is more than one combination, draw only one. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. Separate multiple reactants using the + sign from the drop-down menu. ChemDoodle" Previous Next