The two structures shown below are in equilibrium with one another and are said to be two anomeric forms (or anomers) of glucose. a. Circle all of the following terms that could be used to describe the relationship between these two anomeric forms: isomers, stereoisomers, enantiomers, constitutional isomers, diastereomers. b. Why do the two anomeric forms of glucose rotate plane polarized light but have a different magnitude of specific rotation from one another? c. Label the stereocenter at far right on each structure as R or S as appropriate for both anomeric forms. CH2OH CH2OH OH OH OH OH OH OH OH OH alpha-D-glucopyranose beta-D-glucopyranose

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Chapter23: The Chemistry Of Life
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Problem 65A
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The two structures shown below are in equilibrium with one another and are said to be
two anomeric forms (or anomers) of glucose.
a. Circle all of the following terms that could be used to describe the relationship
between these two anomeric forms: isomers, stereoisomers, enantiomers,
constitutional isomers, diastereomers.
b. Why do the two anomeric forms of glucose rotate plane polarized light but have a
different magnitude of specific rotation from one another?
c. Label the stereocenter at far right on each structure as R or S as appropriate for
both anomeric forms.
CH2OH
CH2OH
OH
OH
OH
OH
OH
OH
OH
OH
alpha-D-glucopyranose
beta-D-glucopyranose
Transcribed Image Text:The two structures shown below are in equilibrium with one another and are said to be two anomeric forms (or anomers) of glucose. a. Circle all of the following terms that could be used to describe the relationship between these two anomeric forms: isomers, stereoisomers, enantiomers, constitutional isomers, diastereomers. b. Why do the two anomeric forms of glucose rotate plane polarized light but have a different magnitude of specific rotation from one another? c. Label the stereocenter at far right on each structure as R or S as appropriate for both anomeric forms. CH2OH CH2OH OH OH OH OH OH OH OH OH alpha-D-glucopyranose beta-D-glucopyranose
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