The reaction: A → products can be described by a zero-order rate law. a) Derive the relationship between the concentration of A at the surface of a non- porous catalyst particle (CA,s) and that in the bulk (CA,b). Define X for such a system and rewrite your relationship as CA,s = f(CA,b, x). b) Explain what happens as X increases from near 0 to X> 1 for this system, what type of values do you get for CA,s, and what causes this behavior?

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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The reaction:
A →
products
can be described by a zero-order rate law.
a) Derive the relationship between the concentration of A at the surface of a non-
porous catalyst particle (CA,s) and that in the bulk (CA,b). Define X for such a system and rewrite
your relationship as CA,s = f(CA,b, x).
b) Explain what happens as X increases from near 0 to X> 1 for this system, what type
of values do you get for CA,s, and what causes this behavior?
Transcribed Image Text:The reaction: A → products can be described by a zero-order rate law. a) Derive the relationship between the concentration of A at the surface of a non- porous catalyst particle (CA,s) and that in the bulk (CA,b). Define X for such a system and rewrite your relationship as CA,s = f(CA,b, x). b) Explain what happens as X increases from near 0 to X> 1 for this system, what type of values do you get for CA,s, and what causes this behavior?
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