The AG of the reaction C6H12O6 +602 --> 6CO2 + 6H₂O is -686 kcal/mol glucose The oxidation of glucose can be coupled to the synthesis of ATP. If the coupling is 50% oxidized? Round your answer to the nearest whole number. Type your answer... oxidized. The AG of the reaction how efficient, kcal/mol ADP + P₁--> ATP + H₂O is +7.3 many molecules of ATP can be synthesized per molecule ATP synthesized. of glucose
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- The AG of the reaction C6H12O6 + 60₂ --> 6CO₂ + 6H₂O is -686 kcal/mol glucose oxidized. The AG of the reaction ADP + P₁ --> ATP + H₂O is + 7.3 kcal/mol ATP synthesized. The oxidation of glucose can be coupled to the synthesis of ATP. If the coupling is 50% efficient, how many molecules of ATP can be synthesized per molecule of glucose oxidized? Round your answer to the nearest whole number.Decylic acid is a saturated fatty acid that occurs naturally in coconut oil and palm kernel oil. Calculate the net ATP yield when decylic acid undergoes complete B oxidation. The formula of decylic acid is shown below: (Given: The oxidation of one NADH yields 2.5 ATP; the oxidation of one FADH2 yields 1.5 ATP; and the oxidation of one acetyl CoA yields 10 ATP.) O 50 ATP O 52 ATP 66 ATP OH O 64 ATPATP Synthase is known to catalyze the synthesis of ATP with a ΔG°’ close to zero, and a Keq' close to. Why is the value of ΔG°’ different from the known value which is 30.5 kJ/mol (the energy for the reverse of ATP hydrolysis)? If the Keq' value is close to one, how is it ensured that the reaction is driven to the product side and more ATP is obtained?
- Coupled reactions occur where a nonspontaneous reaction is enabled by coupling it to a spontaneous reaction. This approach is common in biological settings. Determine if ATP could be generated by this biochemical reaction. You have calculated that cell potential is +0.637V. An example of a coupled reaction is the first step of glycolysis, the phosphorylation of glucose to form glucose-6-phosphate shown below. The net ∆Gº for this reaction isThe standard free energy variation of the ATP hydrolysis reaction is ΔGº’ = -30.5 kJ / mol ATP + H2O ⇄ ADP + Pi In red blood cells, when the concentration of Pi is 1.6 mM, the real change in energy free is ΔG = - 50'2 kJ / mol. a) Calculate under these conditions what is the ratio [ATP] / [ADP] in the red blood cells. b) Determine the equilibrium constant K 'of the reaction outlined above. c) If the ADP concentration were 0.2mM, what would be the effective concentration of ATP corresponding to equilibrium.Coupled reactions occur where a nonspontaneous reaction is enabled by coupling it to a spontaneous reaction. This approach is common in biological settings. Determine if ATP could be generated by this biochemical reaction. You have calculated that cell potential is +0.637V. An example of a coupled reaction is the first step of glycolysis, the phosphorylation of glucose to form glucose-6-phosphate shown below. kJ/mol The net AG° for this reaction is 1 2 3 н он H. H- H- H H H H 4 6. H. glucose phosphate anion glucose-6-phosphate AG = +14.0 kJ/mol 7 8 9. АТР ADP phosphate anion AG = -30.5 kJ/mol +/- LO
- Deoxynucleotides (deoxynucleoside triphosphates) are the substrates for DNA synthesis. Calculate the number of glucose molecules that must be degraded to generate the energy required for the synthesis of 1000 deoxynucleotides used in DNA synthesis. Assume that glucose is oxidized completely to CO2 and H2O, the malate–aspartate shuttle is in operation, and NADPH is the equivalent of 4 ATPThe formation of glutamine from glutamate and ammonium ions requires 14.2 kJ mol-1 of energy input. It is driven by the hydrolysis of ATP to ADP mediated by the enzyme glutamine synthetase. {a) Given that the change in Gibbs energy for the hydrolysis of ATP corresponds to ΔG = -31 kJ mol-1, under the conditions prevailing in a typical cell , can the hydrolysis drive the formation of glutamine? (b) What amount {in moles) of ATP must be hydrolysed to form 1 mol glutamine? (c) Suppose that the radius of a typical cell is 10 μm and that inside it 106 ATP molecules are hydrolysed each second. What is the power density of the cell in watts per cubic metre (1W = 1 Js- 1)? (d) A computer battery delivers about 15 Wand has a volume of 100 cm3 Which has the greater power density, the biological cell or the battery?The following two reactions are coupled in the last step of glycolysis (catalyzed by the enzyme pyruvate kinase). РЕР + Н.О € Руr + Pi ADP + Pi → ATP + H2O AG° = -14.8 kcal/mol AG° = +7.3 kcal/mol D) The steady-state concentrations of ATP, ADP, and pyruvate in human erythrocytes are 2.24 mM, 0.25 mM, and 0.051 mM, respectively. What would be the concentration of PEP in these cells if the coupled reaction was at equilibrium?
- In order for fatty acids to enter the mitochondria to be catabolized via β-oxidation, they must first be reacted with coenzyme A (reaction ①). Use the equations below to answer parts a-c. ① Fatty Acid + CoA → Fatty Acid—CoA ΔG = ??? ② ATP → AMP + PPi ΔG = ─45.6 kJ/mol ③ PPi → 2 Pi ΔG = ─19.2 kJ/mol ④ Fatty Acid + ATP + CoA → FA—CoA + AMP + 2 Pi ΔG = ─34 kJ/mol a) Calculate ΔG for reaction 1. b) Suppose the formation of the fatty acid--CoA proceeded via the reaction of ATP to ADP instead of AMP. Calculate ΔG for reaction 5. ① Fatty Acid + CoA → Fatty Acid—CoA ΔG = from part a ② ATP → ADP + Pi ΔG = ─30.5 kJ/mol ⑤ Fatty Acid + ATP + CoA → FA—CoA + ADP + Pi ΔG = ??? kJ c) So why does the…What terms would best describe the above coupled reaction? (If the DGo for ATP hydrolysis into ADP + inorganic phosphate is -7.3 kcal/mole, and the DGo for maltose synthesis from glucose + glucose is +3.7 kcal/mole, calculate the standard free energy change for the combined reaction of ATP + glucose + glucose g ADP + maltose + inorganic phosphate.) it is non-spontaneous and endothermic (because the overall DGo is negative) it is spontaneous and exothermic (because the overall DGo is negative) it is non-spontaneous and endothermic (because the overall DGo is positive) it is spontaneous and exothermic (because the overall DGo is positive) it is non-spontaneous and exothermic (because the overall DGo is negative)In the beta oxidation of linoleic acid, converting the 3, 5, 8 trienoyl CoA intermediate back to an expected intermediate for a beta oxidation substrate costs the equivalent of how many ATPs? (hint: look at the 'right side' of the figure for addressing problem 3 with linoleic acid)