Consider the isoelectronic ions Cl- and K+. (a) Which ionis smaller? (b) Using Equation 7.1 and assuming that coreelectrons contribute 1.00 and valence electrons contributenothing to the screening constant, S, calculate Zeff for thesetwo ions. (c) Repeat this calculation using Slater’s rules toestimate the screening constant, S. (d) For isoelectronic ions,how are effective nuclear charge and ionic radius related?

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter5: Electron Configurations And The Periodic Table
Section: Chapter Questions
Problem 117QRT
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Consider the isoelectronic ions Cl- and K+. (a) Which ion
is smaller? (b) Using Equation 7.1 and assuming that core
electrons contribute 1.00 and valence electrons contribute
nothing to the screening constant, S, calculate Zeff for these
two ions. (c) Repeat this calculation using Slater’s rules to
estimate the screening constant, S. (d) For isoelectronic ions,
how are effective nuclear charge and ionic radius related?

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