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- Predict 31PNMR spectrum of cis-[Pt(PR3)2Cl2]. Given that phosphorus-31 (100% abundant), platinum-95 (33% abundant), all have a nuclear spin quantum numbers of (I = ½)Photoelectron spectra were acquired from a sample ofgaseous N2 using He(I) light with energy 21.22 eV as theionization source. Photoelectrons were detected withkinetic energy values 5.63 eV and also with 4.53 eV. Calculate the ionization energy for each group of electrons.Identify the MOs that were most likely the sources ofthese two groups of electrons.Consider the d4 electron configuration of a free ion: a) Calculate the spin multiplicity
- Which is the ground-state electronic configuration of Iron? i. [Ar] 4s23d6 ii. 1s22s22p63s23p64s23d3 iii. 1s22s22p63s23p64s23d6 iv. 1s22s22p63s23p63d34s2The ground state of NO2 is A1 in the group C2v. To what excited states may it be excited by electric dipole transitions, and what polarization of light is it necessary to use?6. What is the electronic configuration for the 26Fe+2: z6Fe+3: 29Cu1: 29Cu 2 :
- For the following atoms determine electronic configurations. Calculate the ground term for each configuration. Plesase explain each step (1) N (2) Mo6+ (3) Cl (4) Cr2+ (5) Nb3+ (6) Ru2+Are the structures of CuCl2(OPPh3)2 and CuCl2(PPh3)2 - d9 or d10 - 1 unpaired electron or no unpaired electron - Cu1+ or Cu2+ - include magnetic moments of eachGive the possible term symbols for (i) Sc [Ar]3d104s2, (ii) Br [Ar]3d104s24p5.
- What terms (expressed as S, D, etc.) can arise from the [He]2s22p 13d1 excited configuration of carbon?5. The ground state of NO2 is A1. To what excited states may it be excited by electric dipole transitions, and what polarizations of light is it necessary to use to get the transition.Using photoelectron spectroscopy, the ionization energy of the least tightly bound valence electron on Cl was determined to be 13.0 eV. Calculate the Zeffective for this electron.