5) Consider the rhodium complex below. Reaction with 1 equivalent of oxygen gas oxidizes the metal centre and gives a new complex with cis, distorted octahedral geometry. Draw the structure of the product and give the oxidation state, valence electron count, and d-electron count for both rhodium complexes. Ar RhN Bu Ph3P.. 1 eq. O2 ? Ph3P"

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter20: Chemistry Of Selected Transition Elements And Coordination Compounds
Section: Chapter Questions
Problem 105QRT
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5) Consider the rhodium complex below. Reaction with 1 equivalent of oxygen gas oxidizes the metal centre
and gives a new complex with cis, distorted octahedral geometry. Draw the structure of the product and give
the oxidation state, valence electron count, and d-electron count for both rhodium complexes.
Ar
1 eq. O2
Ph3P.
Rh
Ph3P
-"Bu
?
Transcribed Image Text:5) Consider the rhodium complex below. Reaction with 1 equivalent of oxygen gas oxidizes the metal centre and gives a new complex with cis, distorted octahedral geometry. Draw the structure of the product and give the oxidation state, valence electron count, and d-electron count for both rhodium complexes. Ar 1 eq. O2 Ph3P. Rh Ph3P -"Bu ?
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