10.4 Complete the following synthesis.a. CH3CH2CH2CO2H from CH3CH2CH=CH2b. CH3CH2CH2CO2H from CH3CH2CH2OH (two ways)c. p-NO2C6H4CO2H from CH3C6H5OHd.☑0002CO₂H from-OHe. CH₂OCH2CO₂H from CH2CH2 (two steps)f. p-CH3C6H4CO2H from toluene

Answered: 10.4 Complete the following synthesis.…

Chemistry

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ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Consider the synthesis below. What is compound Z? CO₂Et CO₂Et 1) KOr-Bu 2) "Y" CO₂Et A.V B. III SOCI D. IV E. 11 EtO₂C CO₂Et IV "z" 1) NaOH/H₂O, heat 2) H30 3) heat (-CO₂) EtO₂C CO₂Et II EtO₂C CO₂Et 0,CO,Et CO₂H III
7. Reaction Scheme. NH₂ NH2 or two differnet methods (no same steps/reagents) C5H12N2 1. xs Mel, xs K2CO3 2. Ag2O, H₂O 3. heat Br2, xs NaOH, xs H₂O OHC 1.03 2. DMS CHO
Select the correct final major product. A 1. B 2. C 3. D 4. 2) CH2MgBr 1. CH₂OH 2. H₂O + HO. major product
Reagent 1 options: CH3MgBrCH3MgBr MgMg CH3CH2CH2MgBrCH3⁢CH2⁢CH2MgBr HOCH2CH2OH,H+HOCH2⁢CH2OH,H+ Reagent 2 Options: CH3CHO 2. H2O CH3CH2CH2CHO 2. H2O Mg Reagent 3 options: CH3Br CH3CH2CH2MgBr CH3MgBr CH3CH2CH2CHO 2. H2O CH3CHO 2. H2O CH3CH2CH2OH Reagent 4 options: CH3MgBr PCC H3O+ CH3Br Reagent 5 options: CH3Br CH3MgBr CH3CH2CH2MgBr Reagent 6 options: H3O+H3⁢O+ PCC NaOH H3O+
3. Choose the appropriate reagent OH HO a. NaCN, then CO2 b. LIAIH4, then CO2 c. NACN, then H2O in HC1 d. LIAIH4, then H2O in HC1
10:4V reaction the 1- pentene with one molecule hydrochloric acid result------ .A CH2CI-CH2-CH2-CH2-CH3 .B CH3-CHCI-CH2-CH2-CH3 .C CH3-CH2-CH2-CH2-CH2CI .D CH3-CH2-CHCI-CH2-CH3
Determine the product of the ff. rxn steps 1. CH;NO2/OH- 2. Sn/HCI 3. ΗΝΟ, A. В. C. OH -NO2 NH2 OH NO2 D.
10. E to CH3ONa a) Br₂ Br2 1. Mg /ether khan (A) (B) (C) (D) hv FeBr3 hv 2. CO2 3. H3O+ C1 B2 B3 B1 KMnO4 H+ C1 Mg, ether CHO b) 1. CH3Mgl H2SO4 HBr 1. Mgether khan A B D to 2. H3O+ peroxide 2. H₂C-CH2 ° CH3COCI AICI 3 1. C1 1. 03 G F E 2. H3O+ 2. Na₂S 3. H3O+
Which is the major product of the following reaction ? CH,CH, H;C-c-CH,CH, CH,CH, H,C-CH-CH=CH2 1 CH;CH, H,C-CH-CH-CH, heat II CH,CH, H,C-c-CH-CH, CHCH; H,C-č-CH,CH, OH II IV a. I b. II C.I d. IV
H2C=CHCH=CH2 H2NCH,CH2CH2CH2CH2CH,NH2 Reagents a. Br2, CH2CI2 КCN, HCN b. LIAIH, then H3o* H2, Pd/C excess NBS, CCI4 excess CH3MgBr, ether then H3O* H3O*, heat C. d. е. f. g. Select reagents from the table to carry out this transformation. (Enter your answer as a single string of letters representing the reagents in the order that you wish to use them, i.e. bdce.)
5. What is the product of the following reaction? [2 points] CHCH3 OH H2SO4 ? heat CH3 Ш. CH=CH2 I. CH3 IV. =CHCH3 II. a. I b. ll C. III V CH2CH3 V.
6) Which of the following sets of reactions accomplish the synthesis shown below? Br H3C-C=CH Br A. 1. NaNHz 2. CH3CH2CH2Br 3. Na/NH3(liq) 4. HBr B. 1. NaOH 2. CH3CH₂Br 3. H₂, Lindlar cat 4. Br₂/H₂O C. 1. NaNH2 2. CH3CH₂l 3. H2, Lindlar cat 4. Br2 D. 1. H₂, Lindlar cat 2. NaNH2 3. CH3CH₂Br 4. Br₂ E. 1. Na/NH3(liq) 2. NaNH2 3. CH3CH₂I 4. HBr

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10.4 Complete the following synthesis. a. CH3CH2CH2CO2H from CH3CH2CH=CH2 b. CH3CH2CH2CO2H from CH3CH2CH2OH (two ways) c. p-NO2C6H4CO2H from CH3C6H5 OH d. ☑0002 CO₂H from -OH e. CH₂OCH2CO₂H from CH2CH2 (two steps) f. p-CH3C6H4CO2H from toluene